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Laser Induced Fluorescence (LIF) Spectroscopy 

Laser Induced Fluorescence Spectroscopy (LIF) takes advantage of a laser source to excite a material to a higher energy state. The subsequent relaxation of the material to a lower energy state produces photon emission through the process of fluorescence. In many cases the resultant emission spectrum can show characteristic spectral features, allowing discrimination of materials. It is particularly useful for characterising organic materials and semi-conductors. We offer LIF spectral imaging in a range of working distances from centimetres to tens of meters. We use a range of excitation laser sources from UV to Near Infrared. The detection spectral range is 400-1000 nm. 

 

Laser induced Fluorescence spectroscopy (LIF) can be used to complement other spectroscopy techniques such as Raman and reflectance spectroscopy to identify and characterise materials. Remote UV LIF spectroscopy at standoff distances of upto tens of metres can be used to conveniently analyse any spot on a monument/object from the ground level without having to move the instrument. Given the non-invasive nature of the technique, it can also be used for mapping an area remotely (fluorescence mapping).

Imaging and Sensing for Archaeology, Art History and Conservation (ISAAC)'s Laser Induced Fluorescence (LIF) Spectroscopy

In-house remote LIF spectrometer in action

applications of LIF Spectroscopy
  • Material identification (eg organics and semi-conductors)

isaac instrumentation

System

Remote

UV/ LIF

Remote

Raman / LIF

Developer

ISAAC Lab

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ISAAC Lab

Excitation Wavelength 

355 nm

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785 nm

Working

Distance

3- 30 m​

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3 - 20 m

Spectral

Resolution

2.8 nm

4 cm -1

Spot Size

~ 1 mm

1 mm

Service

MOLAB/

FIXLAB​

MOLAB/

FIXLAB​

LIF spectroscopy for material identification

LIF_plots.jpg

(a) Reflectance spectral comparison between cadmium red (blue curve) and vermilion (red curve) references in oil. These pigments have similar spectral features, with their inflection points being at close wavelengths, making their distinction difficult. (b) LIF spectral comparison shows a clear difference between cadmium red and vermilion, complimenting their identification.

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